Do you mean that your DC transformer has + and -, and you're not sure how to connect them to the + and - of your amp?
Do not connect anything!!! return all your equipment in it's original packaging to your retailer ASAP, and get a refund.
If they ask why, just tell them you're too $%^&**& stupid to own this type of equipment!!! JK, but I couldn't resist

...I've been waiting for 8 years to use that line.
Seriously...How many amps or watts output does your transformer have?
You are going to need whatever the total of the fuses on your amp have, plus 10 amps, to be safe.
For example if your amp has 2x30 amp fuses, you should have a 70 amp power supply.
Connect the positives of the amp to the positive of the supply, connect the negative of the amp to the negative of the supply, and to the chassis of the computer.
All 120 volt equpiment should also be properly grounded with a 3 prong plug.
Turn it on and check for escaping smoke BEFORE connecting any RCAs.